ESTUDO PRELIMINAR DO USO DOS FINOS DO RESÍDUO DA AREIA VERDE DE FUNDIÇÃO NO DESENVOLVIMENTO DE PASTAS GEOPOLIMÉRICAS
DOI:
https://doi.org/10.46421/entac.v18i.1039Keywords:
Green Foundry Sand Waste, Geopolymers, Compressive strenghtAbstract
In the process of casting metal parts, the molds are produced with a mixture of natural sand and bentonite, however, after heating, the activated bentonite loses its binding properties, causing part of the foundry sand to be discarded from the process. Aiming then to reuse the green foundry sand waste (GFSW) that is discarded in the metal smelting process, the present work had as main aim to evaluate the possibility of replacing the metakaolin with the GFSW fines in the development of a geopolymeric material. Five levels of substitution were studied (0%, 25%, 50%, 75% and 100%). The geopolymers were synthesized using an alkali percentage of 20%, a silica module of 0.5 and a water/solid ratio of 0.45. The specimens were submitted to the compressive strength test for three different cure times (7, 14 and 28 days). The results showed that when replacing the metakaolin by GFSW, the compressive strength decreased significantly, but adjustments in the curing process and in the compositions of the activators can improve the results allowing the use of GFSW in the development of geopolymers.
References
ABIFA, anuário 2019. 18 p. Disponível em: <http://www.abifa.org.br/revista20/#p=1>. Acesso em 11 maio 2020.
AIN, N.; SANI, M.; MAN, Z.; SHAMSUDDIN, R.M.; AZIZLI, K.A.; SHAARIA, K.Z.K. Determination of Excess Sodium Hydroxide in Geopolymer by Volumetric Analysis. Procedia Engineering, ScienceDirect, Perak, v. 148, p. 298–301, 2016.
ANDRADE, L. B.; CARNIN, R. L. P.; PINTO, R. C. A. Areia descartada de fundição para uso em concreto de cimento Portland: análise do agregado. Revista Matéria. Scielo, Florianópolis, v.23, n.03, 2018.
ASSOCIAÇÃO BRASILEIRA DE NORMAS TÉCNICAS. NBR 7215:1996 – Cimento Portland: determinação da resistência à compressão. Rio de Janeiro, 1996.
BELL, Jonathan L.; DRIEMEYER, Patrick E.; KRIVEN, Waltraud M.. Formation of Ceramics from Metakaolin-Based Geopolymers. Part II: k-based geopolymer. Journal Of The American Ceramic Society, [s.l.], v. 92, n. 3, p. 607-615, mar. 2009. Wiley. Disponível em:< http://dx.doi.org/10.1111/j.1551-2916.2008.02922.x>.
CASSEL, L. D. Manifestação patológica em sistemas geopoliméricos produzidos com metacaulim: avaliação da susceptibilidade no desenvolvimento de eflorescências. Porto Alegre, 2018, Trabalho de Conclusão de Curso (Graduação em Engenharia Civil), Universidade Federal do Rio Grande do Sul – UFRGS, Porto Alegre, 2018.
DAVIDOVITS, Joseph. Geopolymers: inorganic polymeric new materials. Journal of Thermal Analysis and calorimetry, v. 37, n. 8, p. 1633-1656, 1991.
DAVIDOVITS, J. Geopolymers: Ceramic-Like Inorganic Polymers. Journal of Ceramic Science and Technology. Google Acadêmico, Saint-Quentin, v.8, n.3, Ago. 2017.
DOğAN-SAğLAMTIMUR, Neslihan. Waste Foundry Sand Usage for Building Material Production: a first geopolymer record in material reuse. Advances In Civil Engineering, [s.l.], v. 2018, p. 1-10, 2018. http://dx.doi.org/10.1155/2018/1927135.
ELAKYAH, D.; KALAIVANI, M.; EASWARAN, P. Effect of curing and molarity on Geopolymer concrete with foundry sand. International Journal of Scientific Research and Review, v. 7, n. 3, 2019.
HU, Z.; WYRZYKOMSKI, M.; LURA, P. Estimation of reaction kinetics of geopolymers at early ages. Cement and Concrete Research, ScienceDirect, Zurich, v. 129, Jan. 2020.
KLINSKY, Luis Miguel Gutiérrez. Proposta de Reaproveitamento de Areia Fundição em Subbases e Bases de Pavimentos Flexíveis Através da sua Incorporação a Solos Argilosos. 185 f.
Dissertação (Mestrado em Engenharia Civil: Transportes) – Escola de Engenharia de São Carlos, Universidade de São Paulo, São Carlos, 2008.
LONGHI, M.A.; RODRÍGUES, E.D.; WALKLEY, B.; ZHANG, Z.; KIRCHHEIM, A.P. Metakaolin-based geopolymers: Relation between formulation, physicochemical properties and efflorescence formation. Composites Part B: Engineering, Porto Alegre, v. 182, 2020.
LONGHI, M.A.; RODRÍGUEZ, E. D.; BERNAL, S. A.; PROVIS, J. L.; KIRCHHEIM, A. P. Valorisation of a kaolin mining waste for the production of geopolymers. Journal of Cleaner Production, Porto Alegre, v. 115, p. 265-272, 2016.ENTAC2020 – Porto Alegre, Brasil, 4 a 6 de novembro de 2020LONGHI, M.A.; ZHANG, Z.; RODRÍGUES, E.D.; KIRCHHEIM, A.P.; WANG, H. Efflorescence of alkali-activated cements (geopolymers) and the impacts on material structures: A critical analysis. Frontiers in Materials, Porto Alegre, v. 6, p. 89, 30 Abr. 2019.
STURM, P.; GLUTH, G. J. G.; BROUWERS, H. J. H,; KÜHNE, H. C. Synthesizing one-part geopolymers from rice husk ash. Construction and Building Materials, ScienceDirect, Berlin, v.124, P. 961-966, Ago. 2016.
WAN, Q.; ZHANG, Y.; ZHANG, R. Using mechanical activation of quartz to enhance the compressive strength of metakaolin based geopolymers. Cement and Concrete Composites.
ScienceDirect, Wuhan, V.111, Abr. 2020.
ZHANG, Z.; PROVIS, J.L.; REID, A.; WANG, H. Fly ash-based geopolymers: the relationship between composition, pore structure and efflorescence. Cement and concrete research, ScienceDirect, Toowoomba, v. 64, p. 30-41, 30 Jan. 2014.