DESENVOLVIMENTO DE CIMENTOS ÁLCALI ATIVADOS COMPOSTOS COM RESÍDUOS DE MINERAÇÃO DE CARVÃO

Authors

  • Bruna Juvêncio Frasson
  • Janaíde Cavalcante Rocha

DOI:

https://doi.org/10.46421/entac.v17i1.1678

Keywords:

By-products, Coal gangue, Alkali-Activated

Abstract

Wastes from coal washing has potential for being use as building materials, from pozzolanic materials to aluminosilicate sources in alkali-activated cements. The aim of this work was to evaluate the use of pre-treated mining residues (RCE and LMDT) in alkali-activated cements by analyzing the performance of different types of alkaline solutions and mechanical behavior of pastes. The results showed that the optimized alkali solutions was the composition of Na2SiO3 + NaOH (solid), because wasn`t appearance of efflorescence and had tendency to hardening. With that definition was mixed pastes to compressive strength test, the results showed low value for AARCE (1.83 MPa) in 24 hours and increase of strength for AALMDT (13.91 MPa). This research demonstrated the potential of using waste from coal mining, mitigating the environmental impacts.

References

ALONSO, S.; PALOMO, A. Alkaline activation of metakaolin and calcium hydroxidemixtures: influence of temperature, activator concentration and solids ratio.

Materials Letters, Madrid, n. 47, p.56-62, jan. 2001.

ASSOCIAÇÃO BRASILEIRA DE NORMAS TÉCNICAS. NBR 16508: Carvão mineral - Teorde umidade - Método de ensaio. Rio de Janeiro, 2016.

__________. NBR 7211: Agregados para concreto - Especificação. Rio de Janeiro,2009.

AYDIN, S.; BARADAN, B. Effect of activator type and content on properties of alkaliactivatedslag mortars. Composites Part B: Engineering, [s.l.], v. 57, p.166-172, fev.2014.

BAKHAREV, T.. Durability of geopolymer materials in sodium and magnesium sulfatesolutions. Cement and Concrete Research, [s.l.], v. 35, n. 6, p.1233-1246, jun. 2005.

CAO, Z.; CAO, Y.; DONG, H.; ZHANG, J.; SUN, C. Effect of calcination condition onthe microstructure and pozzolanic activity of calcined coal gangue. InternationalJournal of Mineral Processing, [s.l.], v. 146, p.23-28, jan. 2016.

CHENG, H.; LIN, KL.; CUI, R.; HWANG, CL.; CHENG, TW.; CHANG, YM.. Effect of solid-toliquidratios on the properties of waste catalyst metakaolin based geopolymers.

Construction and Building Materials, [s.l.], v. 88, p.74-83, jul. 2015.

CUTRUNEO, C. M. N. L.; OLIVEIRA, M. L. S.; WARD, C. R.; HOWER, J. C.; DE BRUM, I. A.S.;SAMPAIO, C. H.; KAUTZMANN, R. M.; TAFFAREL, S. R.; Teixeira, Elba C.; SILVA, L. F.O.. Amineralogical and geochemical study of three Brazilian coal cleaning rejects:Demonstration of electron beam applications. International Journal of Coal Geology,[s.l.], v. 130, p.33-52, ago. 2014.

DNPM Departamento Nacional de Produção Mineral. Anuário Mineral Brasileiro.2010.

DNPM Departamento Nacional de Produção Mineral. Sumário Mineral. 2015.

DONG, Z.; XIA, J.; FAN, C.; CAO, J. Activity of calcined coal gangue fine aggregateand its effect on the mechanical behavior of cement mortar. Construction andBuilding Materials, [s.l.], v. 100, p.63-69, dez. 2015.

DUAN, YF.; WANG, PM. Early Hydration of the Material of Alkali-Activated CoalGangue. Journal of Materials Science & Engineering, Shanghai, v. 4, n. 26, p.511-515,ago. 2008.

-activated fly ash-blast furnaceslag composite. Construction and Building Materials, [s.l.], v. 157, p.737-747, dez.2017.

FRASSON, B. J. Aproveitamento de Subprodutos da Mineração de Carvão paraProdução de Cimentos Álcali Ativados. 2017. 168 f. Dissertação (Mestrado) - Cursode Programa de Pós Graduação em Engenharia Civil, Centro Tecnológico,Universidade Federal de Santa Catarina, Florianópolis, 2018.

FRÍAS, M. ; LA VILLA, R. V.; ROJAS, M. S.; MEDINA, C.; JUAN VALDÉS, A. ScientificAspects of Kaolinite Based Coal Mining Wastes in Pozzolan/Ca(OH)2 System. Journalof the American Ceramic Society, [s.l.], v. 95, n. 1, p.386-391, 1 dez. 2011. Wiley-Blackwell.

FRÍAS, M. ; SANCHEZ DE ROJAS, M.I. ; GARCÍA, R. ; JUAN VALDÉS, A.; MEDINA, C..

Effect of activated coal mining wastes on the properties of blended cement.

Cement and Concrete Composites, [s.l.], v. 34, n. 5, p.678-683, maio 2012.

GARCÍA, R.; VIGIL DE LA VILLA, R.; FRÍAS, M.; RODRIGUEZ, O.; MARTÍNEZ-RAMÍREZ, S.;FERNÁNDEZ-CARRASCO, L.; DE SOTO, I. S.; VILLAR-COCIÑA, E. Mineralogical study ofcalcined coal waste in a pozzolan/Ca(OH)2 system. Applied Clay Science, [s.l.], v.108, p.45-54, maio 2015.

GARCÍA, R.; VIGIL DE LA VILLA, R.; FRÍAS, M.; RODRIGUEZ, O.; MARTÍNEZ-RAMÍREZ, S.;FERNÁNDEZ-CARRASCO, L.; DE SOTO, I. S.; VILLAR-COCIÑA, E.. Mineralogical study ofcalcined coal waste in a pozzolan/Ca(OH)2 system. Applied Clay Science, [s.l.], v.108, p.45-54, maio 2015.

GENG, J. ; ZHOU, M.; LI, Y.; CHEN, Y.; HAN, Y.; WAN, S.; ZHOU, X.; HOU, H. Comparisonof red mud and coal gangue blended geopolymers synthesized through thermalactivation and mechanical grinding preactivation. Construction and BuildingMaterials, [s.l.], v. 153, p.185-192, out. 2017.

GENG, J.; ZHOU, M.; ZHANG, T.; WANG, W.; WANG, T.; ZHOU, X.; WANG, X.; HOU, H.

Preparation of blended geopolymer from red mud and coal gangue withmechanical co-grinding preactivation. Materials and Structures, [s.l.], v. 50, n. 2, p.1-11, 12 dez. 2016.

GONG, C.; LI, D.; WANG, X.; LI, Z. Activity and structure of calcined coal gangue.

Journal of Wuhan University of Technology-Mater. Sci. Ed., [s.l.], v. 22, n. 4, p.749-753,dez. 2007. Springer Nature.

GRANIZO, N.; PALOMO, A.; FERNANDEZ-JIMÉNEZ, A.. Effect of temperature andalkaline concentration on metakaolin leaching kinetics. Ceramics International, [s.l.],v. 40, n. 7, p.8975-8985, ago. 2014.

IEA Internacional Energy Agency. Key Coal Trends. 2016.

JELÍNEK, P.; MARSCHALKO, M.; LAMICH, D.; YILMburning in coal tailing dumps: a case study from the Czech Republic. EnvironmentalEarth Sciences, [s.l.], v. 73, n. 10, p.6601-6612, 22 nov. 2014.

KEFENI, K. K.; MSAGATI, T. A. M.; MAMBA, B. B. Acid mine drainage: Prevention,treatment options, and resource recovery. Journal of Cleaner Production, [s.l.], v. 151,p.475-493, maio 2017.

LI, C.; WAN, J.; SUN, H.; LI, L. Investigation on the activation of coal gangue by a newcompound method. Journal of Hazardous Materials,[s.l.], v. 179, n. 1-3, p.515-520, jul.2010.

LI, D.; SONG, X.; GONG, C.; PAN, Z. Research on cementitious behavior andmechanism of pozzolanic cement with coal gangue. Cement and ConcreteResearch, [s.l.], v. 36, n. 9, p.1752-1759, set. 2006.

LI, C.; SUN, H.; LI, L. A review: The comparison between alkali-activated slag (Si+Ca)and metakaolin (Si+Al) cements. Cement and Concrete Research, [s.l.], v. 40, n. 9,p.1341-1349, set. 2010.

MISZ-KENNAN, M., 2010. Thermal alterations of organic matter in coal waste fromUpper Silesia, Poland. Mineralogia, 41, 105 236.

NICHOL, D.; TOVEY, N.p.. Remediation and monitoring of a burning coal refuse bankaffecting the Southsea Looproad at Brymbo, North Wales. Engineering Geology,Wrexham, v. 1, n. 50, p.309-318, maio 1998.

PELISSER, F. ; GUERRINO, E.L. ; MENGER, M. ; MICHEL, M.D. ; LABRINCHA, J.A..

Micromechanical characterization of metakaolin-based geopolymers. Constructionand Building Materials, [s.l.], v. 49, p.547-553, dez. 2013.

ROVNANÍK, P. Effect of curing temperature on the development of hard structure ofmetakaolin-based geopolymer. Construction and Building Materials, [s.l.], v. 24, n. 7,p.1176-1183, jul. 2010.

SAAVEDRA, W. G. V.; ANGULO, D. E.; GUTIÉRREZ, R. M. de. Fly Ash Slag GeopolymerConcrete: Resistance to Sodium and Magnesium Sulfate Attack. Journal of MaterialsIn Civil Engineering, [s.l.], v. 28, n. 12, p.04016148-04016157, dez. 2016. AmericanSociety of Civil Engineers (ASCE).

SAMSON, G.; CYR, M.; GAO, X. Formulation and characterization of blended alkaliactivatedmaterials based on flash-calcined metakaolin, fly ash and GGBS.

Construction and Building Materials, [s.l.], v. 144, p.50-64, jul. 2017.

SHI, C.; FERNÁNDEZ-JIMÉNEZ, A.; PALOMO, Angel. New cements for the 21st century:The pursuit of an alternative to Portland cement. Cement and Concrete Research,[s.l.], v. 41, n. 7, p.750-763, jul. 2011.

SIMATE, G. S.; NDLOVU, S. Acid mine drainage: Challenges and opportunities. Journalof Environmental Chemical Engineering, [s.l.], v. 2, n. 3, p.1785-1803, set. 2014.

SKVÁRA, F.; KOPECKÝ, L.; SMILAUER, V.; BITTNAR, Z. Material and structuralcharacterization of alkali activated low-calcium brown coal fly ash. Journal ofHazardous Materials, [s.l.], v. 168, n. 2-3, p.711-720, set. 2009.

WCI World Coal Institute. The Coal Resource: a comprehensive overview of coal.2009XU, Z.F.; ZOU, X.T.; CHEN, J. Preparation of thermal activation sludge and coalgangue polymer. Intergr Ferro-electr, v.160, n.1, p.1-9.

XU, Z.F.; ZOU, X.T.; YANG, Z. Preparation and properties of sludge and coal ganguecomposite geopolymer. Asian J Chem, [N.I], v.26, n.6, p.327-345.

YAO, Y ; LI, Y ; LIU, XM ; JIANG, SS ; FENG, C ; RAFANAN, E. Characterization on acementitious material composed of red mud and coal industry byproducts.

Construction and Building Materials, [s.l.], v. 47, p.496-501, out. 2013.

YAO, Y.; SUN, H.. A novel silica alumina-based backfill material composed of coalrefuse and fly ash. Journal of Hazardous Materials, [s.l.], v. 213-214, p.71-82, abr. 2012.

ZHANG, Jian et al. Durability of alkali-activated materials in aggressive environments:A review on recent studies. Construction and Building Materials, [s.l.], v. 152, p.598-613, out. 2017.

ZHANG, N.; LI, H.; LIU, X.. Hydration mechanism and leaching behavior of bauxitecalcination-method red mud-coal gangue based cementitious materials. Journal ofHazardous Materials, [s.l.], v. 314, p.172-180, ago. 2016.

ZHOU, C., LIU, G., WU, S., LAM, P.K.S. The environmental characteristics of usage ofcoal gangue in bricking-making: a case study at Huainan, China, 2014,Chemosphere, 95, 274-280.

Published

2018-11-12

How to Cite

FRASSON, Bruna Juvêncio; ROCHA, Janaíde Cavalcante. DESENVOLVIMENTO DE CIMENTOS ÁLCALI ATIVADOS COMPOSTOS COM RESÍDUOS DE MINERAÇÃO DE CARVÃO. In: NATIONAL MEETING OF BUILT ENVIRONMENT TECHNOLOGY, 17., 2018. Anais [...]. Porto Alegre: ANTAC, 2018. p. 2703–2713. DOI: 10.46421/entac.v17i1.1678. Disponível em: https://eventos.antac.org.br/index.php/entac/article/view/1678. Acesso em: 21 nov. 2024.

Similar Articles

1 2 3 4 5 > >> 

You may also start an advanced similarity search for this article.