Compounds in alkaline activation in binary systems between ceramic waste and blast furnace

Authors

DOI:

https://doi.org/10.46421/entac.v20i1.6268

Keywords:

Ceramic waste, Blast furnace slag, Alkaline activation, Ambient temperature curing

Abstract

Ceramic waste, made up of silicon and aluminum, has the potential for use in the development of alkali-activated materials, and granulated blast furnace slag can be a source of calcium that composes binary systems. This research evaluated pastes made by alkali-activation of recycled brick powder (RBP) combined with granulated blast furnace slag (GBFS) and sodium hydroxide activating solution. The precursors were characterized, and after molding and curing the pastes at ambient temperature, compression resistance, XRD, SEM, and FTIR tests validated the occurrence of alkaline activation in the formulations proposed for ages 28 days and 91 days. The PRT50EGAF50 paste presented the highest compressive strength among the samples analyzed (58.39MPa, at 91 days). The formation of dense and cohesive matrices identified in the micrographs, the appearance of the halo between 28o and 30o in XRD, in addition to the displacement of the FTIR bands towards lower wavenumbers, can be related to the presence of amorphous gels, such as CASH, CSH and NASH, indicating effective activation of the aluminosilicates of the residues under study.

Author Biographies

Flávia Müller Grigoleto, CEFET - MG

Master in Materials Engineering from the Federal Center for Technological Education of Minas Gerais and university professor in Sete Lagoas MG and Curvelo MG.

André Guilherme Martins Costa Martins Costa, CEFET MG

Graduating in Materials Engineering at the Federal Center for Technological Education of Minas Gerais.

Augusto Cesar da Silva Bezerra, CEFET MG

PhD in Metallurgical and Mining Engineering from the Federal University of Minas Gerais and tenured professor at the Federal Center for Technological Education of Minas Gerais and coordinator of programs in the Engineering I knowledge area at CAPES.

References

PROVIS, J. L.; BERNAL, S. A. Geopolymers and Related Alkali-Activated Materials. Annual Review of Materials Research, v. 44, n. 1, p. 299–327, 2014.

GIANNOPOULU, I. Et al. Mechanical behavior of construction and demolition waste-based alkali activated materials exposed to fire conditions, Construction and Building Materials, v 415, 2024.

YE, N. et al. Synthesis and strength optimization of one-part geopolymer based on red mud. Construction and Building Materials. v 111, 317–325, 2016.

LEMOUGNA, P.N.; WANG, K.-T.; TANG, Q.; CUI, X.-M. Synthesis and characterization of low temperature (<800 C) ceramics from red mud geopolymer precursor. Construction and Building Materials. V.131, 564–573, 2017.

FAGUNDES, J. T. Obtenção e caracterização de geopolímero a partir da lama vermelha "in natura" e do resíduo da fabricação de vidros planos. Dissertação (mestrado) - Universidade Federal de Ouro Preto. Departamento de Engenharia Civil. Programa de Pós-Graduação em Engenharia das Construções, Ouro Preto, 2019.

ZHANG, Y.; LIU, L. Fly ash-based geopolymer as a novel photocatalyst for degradation of dye from wastewater. Particuology, v. 11, n. 3, p. 353–358, 2013.

NOVAIS, R. M. et al. Synthesis of porous biomass fly ash-based geopolymer spheres for efficient removal of methylene blue from wastewaters. Journal of Cleaner Production, v. 207, p. 350–362, 10 jan. 2019.

PROVIS, J. L. Alkali-activated materials. Cement and Concrete Research, v. 114, p. 40–48, dez. 2018.

ILCAN, H. et al. Low-alkaline activated construction and demolition waste-based geopolymers. Construction and Building Materials, v411, 2024.

BERNAL, S. A. et al. Mechanical and thermal characterisation of geopolymers based on silicate-activated metakaolin/slag blends. Journal of Materials Science, v. 46, n. 16, p. 5477–5486, 2011a.

BREKAILO et al. Avaliação do potencial reativo de adições de resíduos de blocos de cerâmica vermelha e de concreto cominuído de RCD em matriz cimentícia. Cerâmica. v 65, 2019.

LUHAR, I. et al. Assessment of the Suitability of Ceramic Waste in Geopolymer Composites: An Appraisal. Materials v. 14, no. 12: 3279, 21 jun.2021.

METHA, P.M.; MONTEIRO, P.J.M. Concreto: Microestrutura, Propriedades e Materiais. São Paulo, 2ª. ed., 2014, 751p.

DUAN, W. et al. Mitigation of alkali-silica reaction in blast-furnace slag-based alkaline activated material through incorporation of alum water treatment residue. Construction and Building Materials, v406, 2023.

ZHANG, M.; DESKINS, N.A.; ZHANG, G.; CYGAN, R.T.; TAO, M. Modeling the Polymerization Process for Geopolymer Synthesis through Reactive Molecular Dynamics Simulations. The Journal of Physical Chemistry. C 122 ,6760–6773, 2018.

ZHANG, Z. et al. Quantitative kinetic and structural analysis of geopolymers. Part 1. The activation of metakaolin with sodium hydroxide. Thermochimica Acta, v. 539, p. 23–33, 2012.

ABNT - ASSOCIAÇÃO BRASILEIRA DE NORMAS TÉCNICAS. NBR 7215: Cimento Portland - Determinação da resistência à compressão de corpos de prova cilíndricos. Rio de Janeiro, 2019.

SUN, Z.; VOLLPRACHT, A. Isothermal calorimetry and in-situ XRD study of the NaOH activated fly ash, metakaolin and slag. Cement and Concrete Research, v. 103, p. 110–122, 1 jan. 2018.

CHENG, S., GE, K., SUN, T. Pozzolanic activity of mechanochemically and thermally activated coal-series kaolin in cement-based materials. Construction and Building Materials, v. 299, 2021.

MILLER, N. A.; STIRLING, C. D.; NICHOLSON, C. L. The relationship between cure conditions and flexural properties in flyash-based geopolymers. Proceedings of the World Congress Geopolymer, Saint Quentin, France, 28 June–1 July, 121–122p., 2005.

FERNANDEZ-JIMENEZ, A.; PUERTAS, F. Effect of activator mix on the hydration and strength behaviour of alkali-activated slag cements. Advances in Cement Research, v. 15, n. 3, p. 129–136, 2003.

DIAZ, A.G.et al. Improved strength of alkali activated materials based on construction and demolition waste with addition of rice husk ash. Construction and Building Materials, v. 413, 2024.

GARCIA-LODEIRO, I. et al. Compatibility studies between N-A-S-H and C-A-S-H gels. Study in the ternary diagram Na2O–CaO– Al2O3–SiO2–H2O. Cement and Concrete Research, v. 41, n. 9, p. 923–931, 1 set. 2011.

PALOMO, A. et al. Alkaline Activation of Fly Ashes: NMR Study of the Reaction Products. Journal of the American Ceramic Society, v. 87, n. 6, p. 1141–1145, jun. 2004.

YIP, C. K.; LUKEY, G. C.; VAN DEVENTER, J. S. J. The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation. Cement and Concrete Research, v. 35, n. 9, p. 1688–1697, 2005.

SOUZA, L.N.; FIGUEIREDO, P.F.; FRANÇA, S.; SILVA, M.V.S.; BORGES, P.H.R.; BEZERRA, A.C.d.S. Effect of Non-Calcined Sugarcane Bagasse Ash as an Alternative Precursor on the Properties of Alkali-Activated Pastes. Molecules, v. 27, p.1185, 2022.

CORDEIRO, G. C. et al. Ultrafine grinding of sugar cane bagasse ash for application as pozzolanic admixture in concrete. Cement and Concrete Research, v. 39, n. 2, p. 110–115, fev. 2009.

Published

2024-10-07

How to Cite

GRIGOLETO, Flávia Müller; MARTINS COSTA, André Guilherme Martins Costa; DA SILVA BEZERRA, Augusto Cesar. Compounds in alkaline activation in binary systems between ceramic waste and blast furnace . In: NATIONAL MEETING OF BUILT ENVIRONMENT TECHNOLOGY, 20., 2024. Anais [...]. Porto Alegre: ANTAC, 2024. p. 1.12. DOI: 10.46421/entac.v20i1.6268. Disponível em: https://eventos.antac.org.br/index.php/entac/article/view/6268. Acesso em: 25 nov. 2024.

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