Optimization of sulfate content in LC³ cement produced with kaolin flint

Authors

DOI:

https://doi.org/10.46421/entac.v19i1.2191

Keywords:

Sulfate content, Ternary cement, Supplementary Cement Material, Calcined clay

Abstract

Due to the environmental damage caused by the traditional cement manufacturing process, the use of supplementary cementitious materials (SCMs) is an option to reduce the emission of pollutants. In this context, the partial replacement of clinker by calcined clays combined with limestone (LC3 mixtures) is interesting. Thus, the influence of the optimal sulfate content on the production of six different LC3 proposals with kaolin flint was evaluated. The results show that gypsum influenced the kinetics of the initial reactions. The increase in SO3 content accelerated the reaction process of the C3S phase, as well as shifted the sulfate depletion peak.

Author Biography

Samile Raiza Carvalho Matos, Universidade Federal da Bahia

Master in Civil Engineering and PhD student in the area of Civil Construction and Materials. Doctoral student in Civil Engineering at the Federal University of Bahia (Salvador - BA, Brazil).

References

ADU-AMANKWAH, S. et al. Effect of sulfate additions on hydration and performance of ternary slag-limestone composite cements. Construction and Building Materials, v. 164, p. 451–462, 2018.

AMERICAN SOCIETY FOR TESTING AND MATERIALS. C563 − 16 Standard Guide for Approximation of Optimum SO 3 in Hydraulic Cement Using Compressive Strength 1. [s.l: s.n.]. Disponível em: <http://www.copyright.com/>.

ANTONI, M. et al. Cement substitution by a combination of metakaolin and limestone. Cement and Concrete Research, v. 42, n. 12, p. 1579–1589, 2012.

ASSOCIAÇÃO BRASILEIRA DE NORMAS TÉCNICAS. NBR 16605: Cimento Portland e outros materiais em pó — Determinação da massa específicaABNT. Rio de Janeiro: [s.n.].

ASTM. CalorimetryC1679-17 Standard Practice for Measuring Hydration Kinetics of Hydraulic Cementitious Mixtures Using Isothermal Calorimetry. West Conshohocken: ASTM International, 2017.

AVET, F.; SCRIVENER, K. Investigation of the calcined kaolinite content on the hydration of Limestone Calcined Clay Cement (LC3). Cement and Concrete Research, v. 107, n. August 2017, p. 124–135, 2018.

DA SILVA ANDRADE NETO, J.; DE LA TORRE, A. G.; KIRCHHEIM, A. P. Effects of sulfates on the hydration of Portland cement – A review. Construction and Building Materials, v. 279, 2021.

KRISHNAN, S. et al. Hydration kinetics and mechanisms of carbonates from stone wastes in ternary blends with calcined clay. Construction and Building Materials, v. 164, p. 265–274, 10 mar. 2018.

KURDOWSKI, W. Cement and concrete chemistry. [s.l.] Springer Netherlands, 2014. v. 9789400779

LI, X. et al. Reactivity tests for supplementary cementitious materials: RILEM TC 267-TRM phase 1. Materials and Structures/Materiaux et Constructions, v. 51, n. 6, 1 dez. 2018.

LIU, F.; LAN, M. Effects of Gypsum on Cementitious Systems with Different Mineral Mixtures. Key Engineering Materials, v. 509, p. 20–25, 2012.

LOTHENBACH, B.; SCRIVENER, K.; HOOTON, R. D. Supplementary cementitious materials. Cement and Concrete Research, v. 41, n. 12, p. 1244–1256, dez. 2011.

MAIA, A. A. B. et al. Utilização de rejeito de caulim da Amazônia na síntese da zeólita A. Cerâmica, v. 53, n. 327, p. 319–324, set. 2007.

MOREIRA, C.; RÊGO, J. H. S. Effect of Gypsum Content on the Compressive Strength of LC3 Cement. Em: RILEM Bookseries. [s.l.] Springer Netherlands, 2020. v. 22p. 133–139.

PÖLLMANN, H.; DA COSTA, M. L.; ANGELICA, R. Sustainable secondary resources from Brazilian kaolin deposits for the production of calcined clays. RILEM Bookseries, v. 10, p. 21–26, 2015.

SALVI MALACARNE, C. et al. Environmental and technical assessment to support sustainable strategies for limestone calcined clay cement production in Brazil. Construction and Building Materials, v. 310, 6 dez. 2021.

SCRIVENER, K. et al. Calcined clay limestone cements (LC3). Cement and Concrete Research, v. 114, n. August 2017, p. 49–56, 2018.

SCRIVENER, K. L. SPECIAL ISSUE-Future Cements Options for the future of cementThe Indian Concrete Journal. [s.l: s.n.].

ZAJAC, M. et al. Influence of limestone and anhydrite on the hydration of Portland cements. Cement and Concrete Composites, v. 46, p. 99–108, fev. 2014.

ZUNINO, F.; SCRIVENER, K. The influence of the filler effect on the sulfate requirement of blended cements. Cement and Concrete Research, v. 126, 1 dez. 2019.

Published

2022-11-07

How to Cite

DE MEDEIROS, Matheus Henrique Gomes; MATOS, Samile Raiza Carvalho; ZINI, Aline; DESSUY, Thainá Yasmin; RODRIGUEZ, Erich David; KIRCHHEIM, Ana Paula. Optimization of sulfate content in LC³ cement produced with kaolin flint. In: NATIONAL MEETING OF BUILT ENVIRONMENT TECHNOLOGY, 19., 2022. Anais [...]. Porto Alegre: ANTAC, 2022. p. 1–14. DOI: 10.46421/entac.v19i1.2191. Disponível em: https://eventos.antac.org.br/index.php/entac/article/view/2191. Acesso em: 21 nov. 2024.